WORLD IN LAB

WORLD IN LAB

Monday, October 18, 2010

VSEPR MODEL





IntroductionNo lone pairsOne Lone PairTwo Lone PairsThree Lone Pairs
2 Electron Pairs2 Bonding Electron Pairs
3 Electron Pairs3 Bonding Electron Pairs
4 Electron Pairs4 Bonding Electron Pairs3 Bonding Electron Pairs2 Bonding Electron Pairs
5 Electron Pairs5 Bonding Electron Pairs4 Bonding Electron Pairs3 Bonding Electron Pairs2 Bonding Electron Pairs
6 Electron Pairs6 Bonding Electron Pairs5 Bonding Electron Pairs4 Bonding Electron Pairs

VSEPR Model

Electronic Structure and Molecular Shape

Most of the time it is impossible to predict the molecular geometry of a compound based solely on the number of atoms that surround a central atom. For example BF3 has a trigonal planar structure, ammonia NH3has a trigonal pyramidal geometry and iodine trichloride ICl3 has a T-shaped molecular shape.





AMMONIA 
 

IODINE TETRACHLORIDE

 



The VSEPR (Valance Shell Electron Pair Repulsion) theory is based on the principle that electron pairs around an atom repel each other. This is true for bonding electron pairs and lone pairs, which are not involved in bonding. It gives us the possibility to predict and understand the structure of molecules and ions that consist of a central atom and a different number of it surrounding atoms.
The starting point is the Lewis dot structure of the compound. The number of electron pairs around the central atom determines the electron pair geometry. Lone pairs and bonding electron pairs are placed around the central atom.
The final step is to leave out lone pairs and determine the molecular geometry or molecular shape.





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